i've been all thru windows live mail and i can't find the preferences for how often it checks for new mail but if you go to the msn home page you can sign in to hotmail on the right and then you will get notified as soon as you recieve a new email.
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Synology invites you to visit them at IP EXPO - Europe’s number one IT event on 7th-8th October. Register HERE for free and join them at stand DD8