If you bought a full retail "boxed" version of Windows 7 then yes you are quite entitled to move it, you will probably have to ring the Microsoft activation number tho to get it activated on desktop. Make sure its removed from laptop first.
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Synology invite you to their launch event on 16th September 2015. See the unveiling of the new DSM and products live, plus a chance to win a populated NAS! Tickets are free and available now. Click HERE for more details