Try it and see how you get on. Connect the HD data cable to the drive with the red stripe nearest the power socket, plug the power cable into the socket and start her up.
You may have to tell the BIOS about the 2nd drive.
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How to get WWDC 2017 tickets
Synology invites you to visit them at Insomnia on 26th – 29th August. Book your tickets now and visit Synology.