The settings should be
POP server: pop.freeserve.net
SMTP Server: smtp.freeserve.net
Once you have them working you can save the data through Outlook Express: click Tools | Accounts | Export and specify the name of the file to save the settings. The file will be saved as an '.iaf file'and can be save to CD etc.
You can import the settings using the import option in Accounts Be sure to save this information for every account.