Check out Discus. I use it all the time.
It has templates for any label going and it also has a template for printing direct to the CD/DVD.
I have an Epson R220 printer which can print direct on to CD/DVDs. Can't get much more professional that that!
It is a very big program/templates. It started off on CD but now is sent out on DVD. Too big to dowload.
You can download a demo but it prints "DEMO" across the labels.