I have both so yes, maybe?
But only if you have the experience to backup those certs. People expect to get these certs and magically get a fantastic job - just doesn't happen.
If you have no admin/networking experience you will not land one of those posts with just high level certs - YOU NEED EXPERIENCE. Get a position on a 2nd/3rd line xDSL help desk to build up experience, then ,move to LAN support then try to get a job with an ISP (this is the route I took & now have my dream job)
I found the MCSE bored me to tears & I have not really used it but just loved the technical CCNA. I am currently studying for the CCVP.
Good Luck on your studies!