Just checked the spec of both the 5005 and 5006 on Dealtime at click here
I have the 5005 and I can't see any difference except for the price.
I got mine from Argos at £120 and got a £10 voucher as well.
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Synology invites you to visit them at Insomnia on 26th – 29th August. Book your tickets now and visit Synology.